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Study on the high efficiency extraction technology of vanadium by combined extraction centrifugal extractor under acidic condition

Release date:2024.10.29

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In the process of vanadium extraction under acidic conditions, the combined extraction centrifugal extractor, with its unique advantages, has become the key equipment to achieve efficient and accurate separation of vanadium ions. This process not only involves multiple complex chemical steps, but also requires precise control of various operating parameters to ensure extraction efficiency and product quality.


Extraction mechanism of vanadium in acidic environment


In acidic solutions, vanadium mainly exists in the form of VO^2+ plasma, and these ions react with specific extractants (such as organic phosphinates P204, P507 and quaternary ammonium salts Aliquat336) to be effectively extracted into the organic phase. The success of this process is highly dependent on the chemical properties of the extractant and the pH control of the solution.


Application advantages of combined extraction centrifugal extractor


The mass transfer rate between vanadium ion and extractant is accelerated by the powerful centrifugal force field of the combined extraction centrifugal extractor, and the extraction efficiency is significantly improved. At the same time, the optimized mixing and separation mechanism ensures full contact and rapid separation of the two-phase solution, which further improves the stability and controllability of the extraction process.


Detailed explanation of process flow


Raw material pretreatment: the vanadium-containing ore or waste is broken, ground, and leached under acidic conditions to transfer vanadium ions from the solid phase to the liquid phase. In this step, acidity, temperature and time are strictly controlled to maximize vanadium leaching rate.




Solvent extraction preparation: Select the appropriate extractant and adjust its concentration to the optimal range. The extractant with high selectivity and high extraction efficiency is the key to ensure the success of the subsequent extraction process.


Combined extraction centrifugal extraction: the leaching solution and extractant are mixed in a certain proportion and sent to the rotary drum of the combined extraction centrifugal extraction machine. Under the strong centrifugal force generated by high-speed rotation, the two-phase solution is rapidly mixed and mass transfer occurs, and vanadium ions are efficiently extracted into the organic phase. Subsequently, the mixture is automatically separated into clear organic and aqueous phases under the action of centrifugal force, which are respectively extracted through their respective collection systems.


Follow-up treatment and recovery: The vanadium-rich organic phase is reversed extraction operation, and the vanadium ions are dissociated from the organic phase with the appropriate reverse extraction agent. The water phase after stripping is further treated by washing, precipitation, crystallization or electrolysis to recover and purify vanadium products. At the same time, extractants are recycled through appropriate recycling processes, reducing production costs and environmental pollution.




The combined extraction centrifugal extractor shows its unique advantages and application value in the process of extracting vanadium under acidic conditions. An efficient and environmentally friendly vanadium extraction process can be achieved by precisely controlling operation parameters, optimizing extraction agent selection and strengthening equipment maintenance. The application of this technology not only improves the recovery rate of vanadium resources, but also provides strong support for the sustainable development of related industries.

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